How To Print Mailing Labels From Excel [Address List Example] Then, create a new blank document. On the new document, click 'Mailings' from the tab list. Click the 'Start Mail Merge' icon and select 'Labels…'. A window titled 'Label Options' will open. On the 'Label vendors', select 'Avery US Letter'. On the 'Product number', select '5160 Address Labels'. Press 'OK'.